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Why LGM methane needs a bigger wetland collapse

Ice-core CH4 and isotopes imply about a 50% source drop at the LGM; process models underpredict both concentration and isotopic shifts.

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How much did ice-core CH4 rise from LGM to late preindustrial?

From 375 to 680 ppbv.

Source: Bayesian Analysis of the Glacial-Interglacial Methane Increase Constrained by Stable Isotopes and Earth System Modeling · DOI · quote verified

What happened to δ13CH4 over that interval?

It depleted from −43 ± 0.3‰ to −48 ± 0.3‰.

Source: Bayesian Analysis of the Glacial-Interglacial Methane Increase Constrained by Stable Isotopes and Earth System Modeling · DOI · quote verified

What LGM CH4 does the standard-fire process budget produce?

447 ppbv, underestimating the observed drop and isotope shift.

Source: Bayesian Analysis of the Glacial-Interglacial Methane Increase Constrained by Stable Isotopes and Earth System Modeling · DOI · quote verified

What source reduction is needed for LGM CH4?

About 50%; bottom-up emissions fail to match it.

Source: Bayesian Analysis of the Glacial-Interglacial Methane Increase Constrained by Stable Isotopes and Earth System Modeling · DOI · quote verified

How large is the leaf-δ13C effect on atmospheric δ13CH4?

Relatively limited at 0.6‰.

Source: Bayesian Analysis of the Glacial-Interglacial Methane Increase Constrained by Stable Isotopes and Earth System Modeling · DOI · quote verified

What inversion method infers sources?

Metropolis-Hastings MCMC conditioned on ice-core CH4 and isotopes.

Source: Bayesian Analysis of the Glacial-Interglacial Methane Increase Constrained by Stable Isotopes and Earth System Modeling · DOI · quote verified

What geologic source issue is highlighted?

A ~54 TgCH4/year modern geologic source cannot be reconciled with the required LGM source drop.

Source: Bayesian Analysis of the Glacial-Interglacial Methane Increase Constrained by Stable Isotopes and Earth System Modeling · DOI · quote verified

What chlorine-sink change is estimated?

Boundary-layer Cl contributed only 0.12‰ to LGM δ13CH4.

Source: Bayesian Analysis of the Glacial-Interglacial Methane Increase Constrained by Stable Isotopes and Earth System Modeling · DOI · quote verified

Which Earth-system methane study supplies the priors?

Hopcroft et al. (H17) late-preindustrial and LGM simulations.

Source: Bayesian Analysis of the Glacial-Interglacial Methane Increase Constrained by Stable Isotopes and Earth System Modeling · DOI · quote verified

What extra fire scenario improves LGM CH4 at the expense of isotopes?

Low fire: LGM fires set to 10% of preindustrial.

Source: Bayesian Analysis of the Glacial-Interglacial Methane Increase Constrained by Stable Isotopes and Earth System Modeling · DOI · quote verified

Why might δ13CH4 still track CO2 even if leaf discrimination is small?

Covariance among CO2, sea level, and climate, plus geologic/fire sources.

Source: Bayesian Analysis of the Glacial-Interglacial Methane Increase Constrained by Stable Isotopes and Earth System Modeling · DOI · quote verified