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Ice-core oleic acid tracks sub-Antarctic sea ice

Oleic acid in a Bouvet Island ice core covaries with MSA and winter–spring sea ice, suggesting a new marine biomarker.

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Which new organic is proposed as a sea-ice marker?

Oleic acid, a phytoplankton fatty acid.

Source: Organic Compounds in a Sub-Antarctic Ice Core: A Potential Suite of Sea Ice Markers · DOI · quote verified

Where and how long is the Bouvet core?

Eastern slope ~350 m altitude, 14.2 m, dated 2001–2016.

Source: Organic Compounds in a Sub-Antarctic Ice Core: A Potential Suite of Sea Ice Markers · DOI · quote verified

What does PC4 group together?

MSA and oleic acid.

Source: Organic Compounds in a Sub-Antarctic Ice Core: A Potential Suite of Sea Ice Markers · DOI · quote verified

What is the oleic acid–MSA correlation?

r = 0.79 (p < 0.01).

Source: Organic Compounds in a Sub-Antarctic Ice Core: A Potential Suite of Sea Ice Markers · DOI · quote verified

Where is the SIC correlation region?

Along the maximum sea-ice-extent margin west of Bouvet, matching westerly transport.

Source: Organic Compounds in a Sub-Antarctic Ice Core: A Potential Suite of Sea Ice Markers · DOI · quote verified

What organics correlate with later-season ice farther south?

Oxalate, formate, and acetate.

Source: Organic Compounds in a Sub-Antarctic Ice Core: A Potential Suite of Sea Ice Markers · DOI · quote verified

Were terpene SOA preserved in the core?

No continuous terpene SOA records; many SOA compounds were not detected.

Source: Organic Compounds in a Sub-Antarctic Ice Core: A Potential Suite of Sea Ice Markers · DOI · quote verified

Why were C27–C30 fatty acids absent?

They mark terrestrial sources at a remote marine site.

Source: Organic Compounds in a Sub-Antarctic Ice Core: A Potential Suite of Sea Ice Markers · DOI · quote verified

How long were NAME back trajectories?

5-day trajectories for February and September in 2008–2010.

Source: Organic Compounds in a Sub-Antarctic Ice Core: A Potential Suite of Sea Ice Markers · DOI · quote verified

How much PCA variance do the first four components explain?

93%.

Source: Organic Compounds in a Sub-Antarctic Ice Core: A Potential Suite of Sea Ice Markers · DOI · quote verified

Could penguin colonies explain Bouvet oxalate?

Unlikely; 5-day trajectories do not reach Antarctic coastal colonies.

Source: Organic Compounds in a Sub-Antarctic Ice Core: A Potential Suite of Sea Ice Markers · DOI · quote verified